Level, 1 wins each over 2 singles meetings since 2023. Last meeting on 20/09/2026 at Davis Cup, Group I, 1R, SVK-GRE 3-2.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 20/09/2026 | Davis Cup, Group I, 1R, SVK-GRE 3-2 | — | clay | Tsitsipas | |
| 17/09/2023 | Davis Cup, Group I, 1R, GRE-SVK | — | hard | Molcan | 6-7(6) 6-4 3-6 |
| clay | Molcan 0 - 1 Tsitsipas |
| hard | Molcan 1 - 0 Tsitsipas |
| 2026 | Molcan 0 - 1 Tsitsipas |
| 2023 | Molcan 1 - 0 Tsitsipas |
200 wins, 120 losses since 2021 (62.5%).
Last matches: D V D D D
258 wins, 123 losses since 2021 (67.7%).
Last matches: V V D V V
Level, 1 wins each over 2 singles meetings since 2023.
On 20/09/2026, at Davis Cup, Group I, 1R, SVK-GRE 3-2: Stefanos Tsitsipas won.