Ann Li leads 2 to 1 over 3 singles meetings since 2022. Last meeting on 21/10/2025 at Guangzhou Open - Guangzhou.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 21/10/2025 | Guangzhou Open - Guangzhou | Round 1 | hard | Li | 6-4 7-6(4) |
| 08/10/2024 | W100 Cornella de Llobregat | Round 1 | hard | Li | 6-4 6-0 |
| 17/11/2022 | Argentina Open - Buenos Aires | Round 2 | clay | Kasintseva | 3-6 6-1 6-2 |
| hard | Li 2 - 0 Kasintseva |
| clay | Li 0 - 1 Kasintseva |
| 2025 | Li 1 - 0 Kasintseva |
| 2024 | Li 1 - 0 Kasintseva |
| 2022 | Li 0 - 1 Kasintseva |
174 wins, 130 losses since 2021 (57.2%).
Last matches: D D V V V
186 wins, 145 losses since 2021 (56.2%).
Last matches: D D D V D
Ann Li leads 2 to 1 over 3 singles meetings since 2022.
On 21/10/2025, at Guangzhou Open - Guangzhou (Round 1): Ann Li won 6-4 7-6(4).