Ann Li leads 5 to 2 over 7 singles meetings since 2021. Last meeting on 13/10/2026 at Wuhan Open - Wuhan.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 13/10/2026 | Wuhan Open - Wuhan | Round 1 | hard | Li | 6-1 3-0 |
| 25/08/2026 | Abierto GNP Seguros - Monterrey | Round 1 | hard | Li | 1-6 2-6 |
| 19/01/2026 | Australian Open - Melbourne | Round 1 | hard | Li | 6-4 6-7(5) 7-5 |
| 23/10/2025 | Guangzhou Open - Guangzhou | Round 2 | hard | Li | 5-7 2-6 |
| 24/09/2025 | China Open - Beijing | Round 1 | hard | Serrano | 5-7 7-6(5) 5-7 |
| 29/08/2022 | U.S. Open - New York | Round 1 | hard | Serrano | 6-1 3-6 1-6 |
| 24/10/2021 | Tenerife Ladies Open - Tenerife | Final | hard | Li | 1-6 4-6 |
| hard | Serrano 2 - 5 Li |
| 2026 | Serrano 0 - 3 Li |
| 2025 | Serrano 1 - 1 Li |
| 2022 | Serrano 1 - 0 Li |
| 2021 | Serrano 0 - 1 Li |
155 wins, 120 losses since 2021 (56.4%).
Last matches: D D V D V
172 wins, 128 losses since 2021 (57.3%).
Last matches: V D V V V
Ann Li leads 5 to 2 over 7 singles meetings since 2021.
On 13/10/2026, at Wuhan Open - Wuhan (Round 1): Ann Li won 6-1 3-0.